Volts do not usually kill, it will give you a shock that may knock you out and damage you. depends on the amount.
It is the current that kills when it flows through you to earth. A few milliamps will do it. The saying is, The volts will jolt but a mil will kill.
About more than 50V between both wet hands and current is at least 20mA passing through the heart for a deadly kill.
Reiterating the other answers, you need amps, not necessarily volts.
im a huge nerd and i was thinking about modding DnD to include a technomancer class. one of my powers would be to use a device to send electricity through metalic objects and kill people touching them. my question is: how much electricity do i need. im basing my energy on volts, so how many do i need to do that?