Head gasket is blown at the very least.
Possibly other damge as well, but you wont know until the engine is taken apart and inspected.
The water in the cooling system probably froze which put cracks all through your engine. Take it to a professional but you will probably need a new engine
Bad head or intake gasket.
Time for a TEARDOWN! Yippee!
My car is over heating and water is spewing from the top of the motor also have gas and water in motor oil